Global emissions of HFC-143a (CH<sub>3</sub>CF<sub>3</sub>) and HFC-32 (CH<sub>2</sub>F<sub>2</sub>) from in situ and air archive atmospheric observations

Comparison of Thermophysical Properties of HFC 125, 32 and 143a

Reconciling reported and unreported HFC emissions with atmospheric observations.

We infer global and regional emissions of five of the most abundant hydrofluorocarbons (HFCs) using atmospheric measurements from the Advanced Global Atmospheric Gases Experiment and the National Institute for Environmental Studies, Japan, networks. We find that the total CO2-equivalent emissions of the five HFCs from countries that are required to provide detailed, annual reports to the United...

Future atmospheric abundances and climate forcings from scenarios of global and regional hydrofluorocarbon (HFC) emissions

Hydrofluorocarbons (HFCs) are manufactured for use as substitutes for ozone-depleting substances that are being phased out globally under Montreal Protocol regulations. While HFCs do not deplete ozone, many are potent greenhouse gases that contribute to climate change. Here, new global scenarios show that baseline emissions of HFCs could reach 4.0e5.3 GtCO2-eq yr 1 in 2050. The new baseline (or...

Azeotrope of HFC-125 and HFC-143a as an Alternative for R-502

R-502 has been the primary refrigerant for low temperature commercial refrigeration applications for many years. The impending phase-out of CFCs dictates its elimination in the very near future. The identification of alternative(s) for R-502 therefore becomes a high priority. This paper addresses the factors to be evaluated in selecting the best replacement and identifies an azeotropic mixture ...

Recent increases in global HFC-23 emissions

[1] Firn-air and ambient air measurements of CHF3 (HFC23) from three excursions to Antarctica between 2001 and 2009 are used to construct a consistent Southern Hemisphere (SH) atmospheric history. The results show atmospheric mixing ratios of HFC-23 continuing to increase through 2008. Mean global emissions derived from this data for 2006–2008 are 13.5 ± 2 Gg/yr (200 ± 30 10 gCO2equivalent/yr, ...